{2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride

Tan, Kong Wai and Ng, S.W. and Shawish, H.B. and Maah, Mohd Jamil (2010) {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66. M1074-U374. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810031065.

Shawish-2010-{2-_(2-Carbamothioly.pdf - Published Version

Download (912kB)


The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Deprotonated Schiff base ligand; N,O,S-chelating; Phosphine-coordinated Ni; Square-planar geometry; The hydroxy group; Intramolecular O-H; Amino groups; Chloride anion; Hydrogen bonds
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 05 Jul 2013 08:13
Last Modified: 30 Jan 2019 08:54
URI: http://eprints.um.edu.my/id/eprint/8027

Actions (login required)

View Item View Item