Tan, Kong Wai and Ng, S.W. and Shawish, H.B. and Maah, Mohd Jamil (2010) {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66. M1074-U374. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810031065.
![[img]](http://eprints.um.edu.my/style/images/fileicons/application_pdf.png)
|
PDF
Shawish-2010-{2-_(2-Carbamothioly.pdf - Published Version Download (912kB) |
Abstract
The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Additional Information: | Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA |
| Uncontrolled Keywords: | Deprotonated Schiff base ligand; N,O,S-chelating; Phosphine-coordinated Ni; Square-planar geometry; The hydroxy group; Intramolecular O-H; Amino groups; Chloride anion; Hydrogen bonds |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Miss Malisa Diana |
| Date Deposited: | 05 Jul 2013 08:13 |
| Last Modified: | 30 Jan 2019 08:54 |
| URI: | http://eprints.um.edu.my/id/eprint/8027 |
Actions (login required)
 |
View Item |
