Structural and morphological study of mechanochemically synthesized crystalline nanoneedles of Zr-doped carbonated chlorapatite

Nasiri-Tabrizi, B. and Zalnezhad, E. and Pingguan-Murphy, Belinda and Basirun, Wan Jefrey and Hamouda, A.M.S. and Baradaran, S. (2015) Structural and morphological study of mechanochemically synthesized crystalline nanoneedles of Zr-doped carbonated chlorapatite. Materials Letters, 149. pp. 100-104. ISSN 0167-577X, DOI https://doi.org/10.1016/j.matlet.2015.02.125.

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Abstract

Nanosize Zr-doped carbonated chlorapatite (n-ZCCA) was developed as a novel bioceramic by a ball milling process. Results showed that the microstructural characteristics of the product were affected significantly by the degree of substitution and subsequent annealing at 800 degrees C for 1 h. In the absence of zirconium, mechanical activation for 3 h resulted in the formation of carbonated hydroxyapatite (CHA). With the addition of various amounts of zirconium, nanosize Zr-doped carbonated chlorhydroxyapatite (n-ZCCHA) and n-ZCCA were formed as a result of progressive mechanochemical reactions. From the HR-TEM images, the preferential substitution of Zr onto the ac or bc chlorapatite crystal facets (rich in calcium ions) led to a c-axis oriented crystal growth of crystalline nanoneedles with an average size of around 40-60 nm in length and 10-20 nm in width. (C) 2015 Elsevier B.V. All rights reserved.

Item Type:	Article
Funders:	UM High Impact Research Grant (Regenerative Biomechanics of Human Body) from Ministry of Higher Education Malaysia UM-MOHE UM.C/625/1/HIR/MOHE/ENG/44 , University of Malaya RP021C-13AET
Additional Information:	ISI Document Delivery No.: CG2AR Times Cited: 0 Cited Reference Count: 23 Cited References: Arcos D, 2009, J MATER SCI-MATER M, V20, P447, DOI 10.1007/s10856-008-3616-x Bahman Nasiri-Tabrizi, 2014, CERAM INT, V40, P15623 Baradaran S, 2015, MAT SCI ENG C-MATER, V49, P656, DOI 10.1016/j.msec.2015.01.050 Bououdina M, 2014, PHYSICA E, V56, P107, DOI 10.1016/j.physe.2013.08.024 Dorozhkin SV, 2010, BIOMATERIALS, V31, P1465, DOI 10.1016/j.biomaterials.2009.11.050 Erkmen ZE, 2007, J AM CERAM SOC, V90, P2885, DOI 10.1111/j.1551-2916.2007.01849.x Gao BF, 2010, APPL CATAL A-GEN, V375, P107, DOI 10.1016/j.apcata.2009.12.025 Gharehkhani S, 2015, CARBOHYD POLYM, V115, P785, DOI 10.1016/j.carbpol.2014.08.047 Gibson IR, 2002, J BIOMED MATER RES, V59, P697, DOI 10.1002/jbm.10044 Graeve OA, 2010, BIOMATERIALS, V31, P4259, DOI 10.1016/j.biomaterials.2010.02.009 He B, 2010, SUPERCOND SCI TECH, V23, DOI 10.1088/0953-2048/23/2/025016 HENCH LL, 1991, J AM CERAM SOC, V74, P1487, DOI 10.1111/j.1151-2916.1991.tb07132.x Lallemant L, 2014, J EUR CERAM SOC, V34, P1279, DOI 10.1016/j.jeurceramsoc.2013.11.015 Lee SH, 2006, J EUR CERAM SOC, V26, P111, DOI 10.1016/j.jeurceramsoc.2004.10.005 Liu M, 2014, LANGMUIR, V30, P1176, DOI 10.1021/la500131d Maiti GC, 1981, INORG NUCL CHEM, V43, P2633 Martins MA, 2008, J COLLOID INTERF SCI, V318, P210, DOI 10.1016/j.jcis.2007.10.008 Nasiri-Tabrizi B, 2014, MATER LETT, V134, P42, DOI 10.1016/j.matlet.2014.07.026 Okada M., 2012, SCI TECHNOLOGY ADV M, V13, P1 Rayalu SS, 2005, CURR SCI INDIA, V89, P2147 Sarraf M, NASIRI TABRIZICERAM Suryanarayana C, 2001, PROG MATER SCI, V46, P1, DOI 10.1016/S0079-6425(99)00010-9 Yang W, 2013, J MATER CHEM C, V1, P4275, DOI 10.1039/c3tc30550c Nasiri-Tabrizi, Bahman Zalnezhad, Erfan Pingguan-Murphy, Belinda Basirun, Wan Jefrey Hamouda, A. M. S. Baradaran, Saeid Baradaran, Saeid/M-3077-2013; BASIRUN, WAN JEFREY BASIRUN/B-8008-2010; Engineering, Faculty /I-7935-2015 Engineering, Faculty /0000-0002-4848-7052 UM High Impact Research Grant (Regenerative Biomechanics of Human Body) from Ministry of Higher Education Malaysia UM-MOHE UM.C/625/1/HIR/MOHE/ENG/44; University of Malaya RP021C-13AET This research is supported by UM High Impact Research Grant UM-MOHE UM.C/625/1/HIR/MOHE/ENG/44 (Regenerative Biomechanics of Human Body) from the Ministry of Higher Education Malaysia and University of Malaya Grant number RP021C-13AET. 0 ELSEVIER SCIENCE BV AMSTERDAM MATER LETT
Uncontrolled Keywords:	Biomaterials, powder technology, phase transformation, nanoneedles, hydroxyapatite, bioceramics, composites,
Subjects:	T Technology > T Technology (General) T Technology > TA Engineering (General). Civil engineering (General) T Technology > TJ Mechanical engineering and machinery T Technology > TP Chemical technology
Divisions:	Faculty of Engineering
Depositing User:	Mr Jenal S
Date Deposited:	25 Apr 2016 03:20
Last Modified:	31 Jan 2019 07:28
URI:	http://eprints.um.edu.my/id/eprint/15831

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