N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)

Lee, S.M. and Lo, K.M. and Ali, Hapipah Mohd (2010) N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M161-U706. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810001133.

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The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond between the amido N atom and hydroxy H atom in the Schiff base ligand helps to stabilize the overall molecular structure.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 01 Apr 2013 02:20
Last Modified: 29 Jan 2019 08:57
URI: http://eprints.um.edu.my/id/eprint/5281

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