Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)

Adrian, R.A. and Gonzalez, D.M. and Tiekink, E.R.T. and Walmsley, J.A. (2010) Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M957-U903. ISSN 1600-5368,

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The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)degrees. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C-H...N and C-H...O hydrogen-bonding interactions stabilizes the crystal packing.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 04 Feb 2015 02:16
Last Modified: 31 Jan 2019 01:39
URI: http://eprints.um.edu.my/id/eprint/12529

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