Adrian, R.A. and Gonzalez, D.M. and Tiekink, E.R.T. and Walmsley, J.A. (2010) Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M957-U903. ISSN 1600-5368,
Full text not available from this repository.Abstract
The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)degrees. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C-H...N and C-H...O hydrogen-bonding interactions stabilizes the crystal packing.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Subjects: | Q Science > Q Science (General) |
| Depositing User: | Mr Faizal 2 |
| Date Deposited: | 04 Feb 2015 02:16 |
| Last Modified: | 31 Jan 2019 01:39 |
| URI: | http://eprints.um.edu.my/id/eprint/12529 |
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