N-[(9-Ethyl-9H-carbazol-3-yl)methylidene]-3,4-dimethylisoxazol-5-amine

Tan, Kong Wai and Ng, S.W. and Asiri, A.M. and Khan, S.A. (2010) N-[(9-Ethyl-9H-carbazol-3-yl)methylidene]-3,4-dimethylisoxazol-5-amine. Acta Crystallographica Section E: Structure Reports Online, 66. O2046-U1453. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810027686.

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Abstract

The azomethine double bond in the title Schiff base, C(20)H(19)N(3)O, has an E configuration. The 13-membered carbazolyl fused ring system [r.m.s. deviation = 0.023 (9) A] is nearly coplanar with the five-membered pyrazole ring [r.m.s. deviation = 0.003 (4) A]; the dihedral angle between the two systems is 10.8 (2)degrees. The crystal studied was a non-merohedral twin having a 35% minor component.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	Azomethine; Double bond; Schiff base; Carbazolyl fused ring system; Coplanar; Pyrazole ring; Dihedral angle; Crystal; Non-merohedral twin
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	05 Jul 2013 08:54
Last Modified:	30 Jan 2019 08:50
URI:	http://eprints.um.edu.my/id/eprint/8015

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