Yusoff, R. and Aroua, Mohamed Kheireddine and Shamiri, A. and Ahmady, A. and Jusoh, N.S. and Asmuni, N.F. and Bong, L.C. and Thee, S.H. (2013) Density and viscosity of aqueous mixtures of N-Methyldiethanolamines (MDEA) and ionic liquids. Journal of Chemical and Engineering Data, 58 (2). pp. 240-247. ISSN 0021-9568, DOI https://doi.org/10.1021/Je300628e.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/je300628e
Abstract
The density and viscosity of aqueous mixtures of N-methyldiethanolamine (MDEA) and the ionic liquids (ILs) 1-n-butyl-3-methylimidazolium tetrafluoroborate (bmimBF4), 1-butyl-3-methylimidazolium dicyanamide (bmimDCA), and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate (emimOTf) were determined. The measurements were carried out at 1 atm pressure and temperatures ranging from (303.15 to 363.15) K. The concentration of MDEA was fixed at (2.0 and 4.0) M, whereas the IL concentration was varied from (0.5 to 2.0) M. Both densities and viscosities were increased with increasing IL concentration. Correlation equations of density and viscosity for pure substances and for MDEA and ILs aqueous mixtures as a function of temperature and concentration of MDEA and ILs were also determined. The linear correlation for density had an excellent accuracy with less than 0.98 % deviation for all aqueous mixtures of MDEA and ILs. Meanwhile, the extended Arrhenius equation for viscosity achieved acceptable precision with less than 30 % of deviation from experimental data except for 2.0 M MDEA and 1.5 M bmimDCA mixtures.
| Item Type: | Article |
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| Funders: | UNSPECIFIED |
| Additional Information: | Export Date: 21 April 2013 Source: Scopus CODEN: JCEAA :doi 10.1021/je300628e Language of Original Document: English Correspondence Address: Yusoff, R.; Department of Chemical Engineering, Faculty of Engineering, University Malaya, 50603 Kuala Lumpur, Malaysia; email: ryusoff@um.edu.my References: Ahmady, A., Aroua, M.K., Hashim, M.A., Absorption of Carbon Dioxide in the Aqueous Mixtures of Methyldiethanolamine with Three Types of Imidazolium-Based Ionic Liquids (2011) Fluid Phase Equilib., 309, pp. 76-82; Brennecke, J.F., Maginn, E.J., Ionic liquids: Innovative fluids for chemical processing (2001) AIChE J., 47, pp. 2384-2389; Gordon, C.M., New developments in catalysis using ionic liquids (2001) Appl. Catal. A: Gen., 222, pp. 101-117; Holbrey, J.D., Seddon, K.R., Ionic Liquids (1999) Clean Technol. Environ. Policy, 1, pp. 223-236; Welton, T., Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis (1999) Chem. Rev., 99, pp. 2071-2083; Zhao, D., Wu, M., Kou, Y., Min, E., Ionic liquids: Applications in catalysis (2002) Catal. Today, 74, pp. 157-189; Blanchard, L.A., Gu, Z., Brennecke, J.F., High-Pressure Phase Behavior of Ionic Liquid/CO2 Systems (2001) J. Phys. Chem. B, 105, pp. 2437-2444; Anthony, J.L., Aki, S.N.V.K., Maginn, E.J., Brennecke, J.F., Feasibility of using ionic liquids for carbon dioxide capture (2004) Int. J. Environ. Technol. Manage., 4, pp. 105-115; Cadena, C., Anthony, J.L., Shah, J.K., Morrow, T.I., Brennecke, J.F., Maginn, E.J., Why Is CO2 so Soluble in Imidazolium-Based Ionic Liquids? (2004) J. Am. Chem. Soc., 126, pp. 5300-5308; Camper, D., Scovazzo, P., Koval, C., Noble, R., Gas Solubilities in Room-Temperature Ionic Liquids (2004) Ind. Eng. Chem. Res., 43, pp. 3049-3054; Scovazzo, P., Camper, D., Kieft, J., Poshusta, J., Koval, C., Noble, R., Regular Solution Theory and CO2 Gas Solubility in Room-Temperature Ionic Liquids (2004) Ind. Eng. Chem. Res., 43, pp. 6855-6860; Ahmady, A., Aroua, M.K., Hashim, M.A., Density, Viscosity, Physical Solubility and Diffusivity of Carbon Dioxide in Aqueous Mixtures of MDEA and Ionic Liquid bmimBF4 (2011) Chem. Eng. J., 172, pp. 763-770; Shiflett, M.B., Niehaus, A.M.S., Yokozeki, A., Separation of CO2 and H2S Using Room-Temperature Ionic Liquid bmimMeSO4 (2010) J. Chem. Eng. Data, 55, pp. 4785-4793; Ahmady, A., Aroua, M.K., Hashim, M.A., Experimental investigation on the CO2 solubility and its initial rate of absorption in aqueous mixtures of MDEA with the ionic liquid bmimBF4 (2010) J. Chem. Eng. Data, 55, pp. 5733-5738; Keskin, S., Kayrak-Talay, D., Akman, U., Hortacsu, O., A review of ionic liquids towards supercritical fluid applications (2007) J. Supercrit. Fluids, 43, pp. 150-180; Aki, S.N.V.K., Mellein, B.R., Saurer, E.M., Brennecke, J.F., High-Pressure Phase Behavior of Carbon Dioxide with Imidazolium-Based Ionic Liquids (2004) J. Phys. Chem. B, 108, pp. 20355-20365; Muldoon, M.J., Aki, S.N.V.K., Anderson, J.L., Dixon, J.K., Brennecke, J.F., Improving Carbon Dioxide Solubility in Ionic Liquids (2007) J. Phys. Chem. B, 111, pp. 9001-9009; Feng, Z., Jing-Wen, M., Zheng, Z., You-Ting, W., Zhi-Bing, Z., Study on the absorption of carbon dioxide in high concentrated MDEA and ILs solutions (2012) Chem. Eng. J., 181-182, pp. 222-228; Quijada-Maldonado, E., Van Der Boogaart, S., Lijbers, J.H., Meindersma, G.W., De Haan, A.B., Experimental densities, dynamic viscosities and surface tensions of the ionic liquids series 1-ethyl-3-methylimidazolium acetate and dicyanamide and their binary and ternary mixtures with water and ethanol at T = (298.15 to 343.15 K) (2012) J. Chem. Thermodyn., 51, pp. 51-58; Zhao, Y., Zhang, X., Zeng, S., Zhou, Q., Dong, H., Tian, X., Zhang, S., Density, Viscosity, and Performances of Carbon Dioxide Capture in 16 Absorbents of Amine + Ionic Liquid + H2O, Ionic Liquid + H 2O, and Amine + H2O Systems (2010) J. Chem. Eng. Data, 55, pp. 3513-3519; Domanska, U., Zawadzki, M., Lewandrowska, A., Effect of temperature and composition on the density, viscosity, surface tension, and thermodynamic properties of binary mixtures of N- octylisoquinolinium bis{(trifluoromethyl)sulfonyl}imide with alcohols (2012) J. Chem. Thermodyn., 48, pp. 101-111; Zuniga-Moreno, A., Galicia-Luna, L.A., Bernal-Garcia, J.M., Iglesias-Silva, G.A., Densities, Excess Molar Volumes, Isothermal Compressibilities, and Isobaric Thermal Expansivities of the N-Methyldiethanolamine (1) + Water (2) System at Temperatures between (313 and 363) K and Pressures up to 20 MPa (2007) J. Chem. Eng. Data, 52, pp. 1988-1995; Harris, K.R., Kanakubo, M., Woolf, L.A., Temperature and Pressure Dependence of the Viscosity of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate: Viscosity and Density Relationships in Ionic Liquids (2007) J. Chem. Eng. Data, 52, pp. 2425-2430; Carvalho, P.J., Regueira, T., Santos, L.M.N.B.F., Fernandez, J., Coutinho, J.A.P., Effect of Water on the Viscosities and Densities of 1-Butyl-3- methylimidazolium Dicyanamide and 1-Butyl-3-methylimidazolium Tricyanomethane at Atmospheric Pressure (2010) J. Chem. Eng. Data, 55, pp. 645-652; Van Valkenburg, M.E., Vaughn, R.L., Williams, M., Wilkes, J.S., (2003) Ionic Liquid Heat Transfer Fluids, , In the Fifteenth Symposium on Thermophysical Properties, Boulder, CO; Jacquemin, J., Husson, P., Padua, A.A.H., Majer, V., Density and viscosity of several pure and water-saturated ionic liquids (2006) Green Chem., 8, pp. 172-180; Bernal-Garcia, J.M., Galicia-Luna, L.A., Hall, K.R., Ramos-Estrada, M., Iglesias-Silva, G.A., Viscosities for Aqueous Solutions of N-Methyldiethanolamine from 313.15 to 363.15 K (2004) J. Chem. Eng. Data, 49, pp. 864-866; Geng, Y., Chen, S., Wang, T., Yu, D., Peng, C., Liu, H., Hu, Y., Density, viscosity and electrical conductivity of 1-butyl-3- methylimidazolium hexafluorophosphate + monoethanolamine and + N, N -dimethylethanolamine (2008) J. Mol. Liq., 143, pp. 100-108; Buchheit, B., Baltus, R.E., The Effect of Water and Light Alcohols on the Viscosity of Ionic Liquids (2002) Ph.D. Thesis Proposal; Seddon, K.R., Stark, A., Torres, M.J., Influence of chloride, water, and organic solvents on the physical properties of ionic liquids (2000) Pure Appl. Chem., 72, pp. 2275-2287; Chakrabarty, D., Chakraborty, A., Hazra, P., Seth, D., Sarkar, N., Dynamics of photoisomerisation and rotational relaxation of 3, 3 -diethyloxadicarbocyanine iodide in room temperature ionic liquid and binary mixture of ionic liquid and water (2004) Chem. Phys. Lett., 397 (13), pp. 216-221; Sanchez, G.L.M., Meindersma, G.W., De Haan, A.B., Solvent Properties of Functionalized Ionic Liquids for CO2 Absorption (2007) Chem. Eng. Res. Des., 85, pp. 31-39 |
| Uncontrolled Keywords: | 1-ethyl-3-methylimidazolium trifluoromethanesulfonate; bmimBF; Aqueous mixtures; Arrhenius equation; Correlation equation; Dicyanamide; Experimental datum; Ionic liquid (ils); Linear correlation; N-methyldiethanolamine; Pressure and temperature; Pure substances; Tetrafluoroborates; Mixtures; Viscosity; Ionic liquids. |
| Subjects: | T Technology > TA Engineering (General). Civil engineering (General) T Technology > TP Chemical technology |
| Divisions: | Faculty of Engineering |
| Depositing User: | Mr Jenal S |
| Date Deposited: | 16 Jul 2013 01:43 |
| Last Modified: | 31 May 2019 04:26 |
| URI: | http://eprints.um.edu.my/id/eprint/7382 |
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