CdSe/TiO2 nanotubes for enhanced photoelectrochemical activity under solar illumination: Influence of soaking time in CdSe bath solution

Lai, Chin Wei and Lau, Kung Shiuh and Chou, Pui May (2019) CdSe/TiO2 nanotubes for enhanced photoelectrochemical activity under solar illumination: Influence of soaking time in CdSe bath solution. Chemical Physics Letters, 714. pp. 6-10. ISSN 0009-2614, DOI https://doi.org/10.1016/j.cplett.2018.10.054.

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Official URL: https://doi.org/10.1016/j.cplett.2018.10.054

Abstract

In the present study, nanotubular structure of cadmium selenide/titanium dioxide (CdSe/TiO2) was successfully prepared via chemical bath deposition (CBD) chemosynthesis method to improve photoelectrochemical activity under solar illumination. The results revealed that optimum CdSe dopants incorporated into TiO2 nanotubes played a crucial role in determining the photoelectrode performance in water splitting. It was found that synthesized CdSe/TiO2 nanotubes soaked at 30 min of CdSe precursor showed a maximum photocurrent density of 0.0016 A/cm2 with improvement of about 10% than that of pure TiO2 nanotubes under solar illumination. The presence of optimum contents of CdSe dopants incorporated into TiO2 nanotubes could act as efficient mediators for trapping photo-induced electrons and reduce the recombination losses of charge carriers significantly.

Item Type: Article
Funders: University Malaya Research Grant (No. RP045B-17AET), University Malaya Research Fund Assistance (BKP) Grant (No. BK096-2016), Global Collaborative Programme – SATU Joint Research Scheme (No. ST008-2017)
Uncontrolled Keywords: CdSe/TiO2 nanotubes arrays; Photoelectrochemical activity; Chemical bath deposition; Recombination losses; Charge carriers
Subjects: T Technology > TA Engineering (General). Civil engineering (General)
Divisions: Nanotechnology & Catalysis Research Centre
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 17 Jan 2019 04:32
Last Modified: 17 Jan 2019 04:32
URI: http://eprints.um.edu.my/id/eprint/20043

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