Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Saharin, S.M. (2011) Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II). Acta Crystallographica Section E: Structure Reports Online, 67. M513-U1123. ISSN 1600-5368, DOI

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In the title compound, [Ni(NCS)(2)(C11H17N3)(H2O)], the NiII ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O-H...S hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H...pi interactions. The -CH2-N(CH3)(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 25 Mar 2013 01:49
Last Modified: 31 Jan 2019 04:13

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