Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium

Salga, M.S. and Khaledi, H. and Ali, Hapipah Mohd (2011) Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium. Acta Crystallographica Section E: Structure Reports Online, E67. m927. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022100.

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In the title compound, [CdCl2(C14H21N3O2)], the Schiff base ligand chelates the Cd-II ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent molecules are linked through C-H center dot center dot center dot pi interactions into infinite chains along the a axis. The molecules are further connected into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl interactions. The ethylene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.

Item Type: Article
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords: Ligands; Crystal
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 21 Mar 2013 02:59
Last Modified: 30 Jan 2019 00:56
URI: http://eprints.um.edu.my/id/eprint/5202

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