Zheng, Yan-Zhen and Ng, Seik Weng (2005) catena-Poly[[bis(μ-1,10-phenanthrolin-2-olato-κ3N,N′:O)dicopper(I,II)(Cu—Cu)]-μ-chlorocopper(I)-μ-chloro]. Acta Crystallographica Section E: Structure Reports Online, 61 (6). m1030-m1032. ISSN 1600-5368, DOI

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In the crystal structure of the title compound, [Cu3(C 12H7N2O)2Cl2] n, the mixed-valence CuI/CuII cation and the cuprate(I) anion both lie on centres of inversion. The O atom of one half of the planar N,N′-chelated dinuclear copper cation binds to the Cu atom of the other half; the geometry around the metal atom is square-planar, owing to the symmetry-related metal atom at a distance of 2.3945 (5) Å. The dinuclear cations are bridged through the anions to form an infinite linear chain. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.

Item Type: Article
Uncontrolled Keywords: Tautomers; Dione; Ligands
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 06 Aug 2020 08:02
Last Modified: 06 Aug 2020 08:02

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