Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate

Zhou, Yan-Ling and Zeng, Ming-Hua and Ng, Seik Weng (2006) Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 62 (4). m663-m665. ISSN 1600-5368, DOI

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In the title compound, [Co(C19H12N5) 3]·2H2O, three mono-deprotonated 2,5-bis(benzimidazolyl)pyridine heterocycles chelate to cobalt(III) through the N atom of one benzimidazolyl arm of the heterocycle as well as through the pyridyl N atom to form a fairly regular six-coordinate, octahedral geometry geometry for cobalt. A network of N-H⋯N, N H⋯O and O -H⋯N hydrogen bonds involving the non-coordinated water molecules results in a layered structure. © 2006 International Union of Crystallography All rights reserved.

Item Type: Article
Uncontrolled Keywords: Cobalt; Oxygenation; 4-Toluic Acid
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 06 Aug 2020 06:33
Last Modified: 06 Aug 2020 06:33

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