Diaquabis(1,10-phenanthroline-κ2N,N′)zinc(II) 2-hydroxy-5-sulfonatobenzoate tetrahydrate

Zhang, Kou-Lin and Yang, Bo and Ng, Seik Weng (2009) Diaquabis(1,10-phenanthroline-κ2N,N′)zinc(II) 2-hydroxy-5-sulfonatobenzoate tetrahydrate. Acta Crystallographica Section E: Structure Reports Online, 65 (2). m239-m240. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536809003055.

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Official URL: https://doi.org/10.1107/S1600536809003055


The water-coordinated metal centre in the title salt, [Zn(C12H8N2)2(H2O)2] C7H4O6S·4H2O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa-hedral environment. The cation, dianion and solvent water mol-ecules inter-act by O - H⋯O hydrogen bonds to form a layer motif. The SO3 group is disordered over two positions with respect to the O atoms in a 0.76 (1):0.24 (1) ratio. One of the solvent water molecules is also disordered over two positions in a 0.56 (4):0.44 (4) ratio.

Item Type: Article
Uncontrolled Keywords: Metal-Organic Framework; Sulphonate; Benzene 1,3-Disulphonate
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 21 Jul 2020 07:04
Last Modified: 21 Jul 2020 07:04
URI: http://eprints.um.edu.my/id/eprint/25148

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