Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]

Zhao, Li-Zhen and Li, Ping and Cao, Bao-Liang and Ng, Seik Weng (2009) Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]. Acta Crystallographica Section E: Structure Reports Online, 65 (6). m629-m629. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536809016882.

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Official URL: https://doi.org/10.1107/S1600536809016882


The title compound, {[Cd(C4H4O6)] ·0.167H2O}n, adopts a three-dimensional network structure in which each CdII ion is chelated by two pairs of carboxyl-ate and hydroxyl O atoms from two tartrate anions, and is additionally linked to two O atoms of two carboxyl-ate groups that are not involved in chelation. The asymmetric unit has four independent cadmium atoms, two of which lie on special positions of 2 site symmetry. The tartrate anions all lie on general positions. All hydroxyl groups are engaged in O - H⋯O hydrogen-bonds, one of which is also bifurcated. The non-coordinating water molecule is situated on a site with half-occupation.

Item Type: Article
Uncontrolled Keywords: Tartaric Acid; Antimony Potassium Tartrate; Metal-Organic Framework
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 13 Jul 2020 08:26
Last Modified: 13 Jul 2020 08:26
URI: http://eprints.um.edu.my/id/eprint/25094

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