Synthesis and properties of alkyl hydrazonates

Aylward, J.B. and Scott, F.L. (1970) Synthesis and properties of alkyl hydrazonates. Journal of the Chemical Society C: Organic, 7. pp. 968-970. ISSN 0022-4952, DOI

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The solvolysis of hydrazonyl bromides in alcohols (methanol, ethanol, or propanol) gave the equivalent alkyl hydrazonates. The best results were obtained by use of alcohols buffered with sodium acetate. The alkyl hydrazonates were found to be more stable than the analogous alkyl imidates and strong acid was required to cleave them. An attempt to effect a Chapman rearrangement of these materials was unsuccessful.

Item Type: Article
Uncontrolled Keywords: Synthesis; properties; alkyl hydrazonates
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Mr Jasny Razali
Date Deposited: 22 Mar 2021 04:15
Last Modified: 22 Mar 2021 04:15

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