Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate

Zhu, Zhi-Biao and Gao, Shan and Ng, Seik Weng and Tiekink, Edward R.T. (2012) Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate. Acta Crystallographica Section E: Structure Reports Online, 68 (4). m492-m493. ISSN 1600-5368, DOI

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The Zn II atom in the title complex, [Zn(C 6H 4O 8S 2)(H 2O) 5] ·5(H 2O), is coordinated by five water mol-ecules and an O atom of a 4,6-dihy-droxy-benzene-1,3-disulfonate dianion. The coord-ination geometry is distorted octa-hedral, with the Zn-O sulfonate bond relatively long compared to the Zn-O water bonds. The coordinated and lattice water mol-ecules inter-act with each other and with the hy-droxy groups and sulfonate ligand through O-H⋯O hydrogen bonds, generating a tightly held three-dimensional network.

Item Type: Article
Uncontrolled Keywords: Crystal structure; Hydrogen bonds; Ref F
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 22 Nov 2019 04:13
Last Modified: 22 Nov 2019 04:13

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