Hemipotassium hemirubidium digallium(III) manganese(II) tris(phosphate) dihydrate

Zhang, Jing and Li, Ping and Liu, Zhi-Hong and Ng, Seik Weng (2011) Hemipotassium hemirubidium digallium(III) manganese(II) tris(phosphate) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 67 (5). i30-i30. ISSN 1600-5368, DOI https://doi.org/10.1107/S160053681101258X.

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Official URL: https://doi.org/10.1107/S160053681101258X


The title manganese(II) substituted gallophosphate, K0.5Rb 0.5- [Ga2Mn(PO4)3(H 2O)2], features a three-dimensional network built of PO4 tetrahedra, GaO5 trigonal bipyramids and MnO 6 octahedra. The RbI and KI ions, which are disordered with respect to each other in a 1:1 ratio, occupy sites within the channels of the framework. The RbI/KI and MnII atoms occupy positions of 2 symmetry, as does one of the two P atoms. The RbI/KI site is surrounded by six O atoms [2.996 (2)-3.178 (4) Å] in an irregularly-shaped coordination environment. O-H⋯O hydrogen bonds between the water molecules and phosphate O atoms consolidate the crystal packing.

Item Type: Article
Uncontrolled Keywords: Crystal structure; Hydrogen bonds; Ref F
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 14 Nov 2019 07:28
Last Modified: 14 Nov 2019 07:28
URI: http://eprints.um.edu.my/id/eprint/23002

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