Zhang, Jia-Xin and Ng, Seik Weng (2011) (Z)-5-Benzenecarbothioyl-1,11-dimethyl-6-phenyl-5H-dibenzo[d,f][1,3]diazepine. Acta Crystallographica Section E: Structure Reports Online, 67 (2). o364-o364. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536811000092.

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Official URL: https://doi.org/10.1107/S1600536811000092


The sevenmembered ring in the title compound, C28H 22N2S, has a twocoordinate N atom as well as a threecoordinate N atom. The ring adopts a boatshaped conformation with two C atoms of one methylphenyl ring as the stern and the threecoordinate N atom as the prow. The N,N-dimethylethanethioamide fragment is nearly planar (r.m.s. deviation = 0.049 Å); the phenyl ring of the benzenecarbothioyl unit connected to the threecoordinate N atom is aligned at 83.72 (4)° with respect to the mean plane of this fragment. Weak intermolecular C -H⋯S hydrogen bonding is present in the crystal structure.

Item Type: Article
Uncontrolled Keywords: Crystal structure; Hydrogen bonds; Ref F
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 14 Nov 2019 07:12
Last Modified: 14 Nov 2019 07:12
URI: http://eprints.um.edu.my/id/eprint/23000

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