Zhang, Xian-Fa and Gao, Shan and Ng, Seik Weng (2011) Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]. Acta Crystallographica Section E: Structure Reports Online, 67 (11). m1593-m1593. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536811042656.

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Official URL: https://doi.org/10.1107/S1600536811042656


In the title polymeric compound, [Cd(C9H12O 4)(C10H8N2)]n, the CdII atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3- dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjacent CdII atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C - C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxylate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo-pentane ring. © Zhang et al. 2011.

Item Type: Article
Uncontrolled Keywords: Transition metals; Aromatic compounds; Homolytic aromatic
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 14 Nov 2019 04:34
Last Modified: 14 Nov 2019 04:34
URI: http://eprints.um.edu.my/id/eprint/22989

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