Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]

Zhou, Fu Lin and Du, Zhi Hua and Ng, Seik Weng (2011) Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]. Acta Crystallographica Section E: Structure Reports Online, 67 (6). m673. ISSN 1600-5368, DOI

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The polymeric title compound, [Ce(C7H3N 2O6)3(C2H6OS) 2] n, exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol-ecules are disordered in a 0.926 (3):0.074 (3) ratio.

Item Type: Article
Uncontrolled Keywords: Ligands; Crystal structure; X-ray diffraction
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Mr. Faizal Hamzah
Date Deposited: 03 Aug 2011 04:36
Last Modified: 14 Nov 2019 03:04

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