Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate

Mandal, T. and Samanta, S. and Broker, G.A. and Zhao, C.G. and Tiekink, E.R.T. (2010) Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate. Acta Crystallographica Section E: Structure Reports Online, 66 (1). O99-U1897. ISSN 1600-5368,

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In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P-C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supramolecular chains mediated by O-H center dot center dot center dot O hydrogen bonds, which propagate in the a-axis direction. A C-H center dot center dot center dot O interaction consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 28 Dec 2015 01:14
Last Modified: 31 Jan 2019 04:43

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