Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II)

Sadeghi, O. and Amini, M.M. and Ng, S.W. (2010) Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II). Acta Crystallographica Section E: Structure Reports Online, 66 (1). M101-U1045. ISSN 1600-5368,

Full text not available from this repository.


In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)(6)O(C4H8O)(H2O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule. In the crystal, adjacent molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn-II atoms are disordered with respect to the Fe-III atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 23 Dec 2015 03:18
Last Modified: 31 Jan 2019 04:51
URI: http://eprints.um.edu.my/id/eprint/15277

Actions (login required)

View Item View Item