tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate

Pinheiro, A.C. and de Souza, M.V.N. and Wardell, S.M.S.V. and Wardell, J.L. and Tiekink, E.R.T. (2010) tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate. Acta Crystallographica Section E: Structure Reports Online, 66 (4). O994-U3669. ISSN 1600-5368,

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In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)degrees, and the carbonyl groups are anti to each other. In the crystal, the hydroxy group forms an O-H center dot center dot center dot N(a) (a = amine) hydrogen bond and each of the four N-H atoms forms an N-H center dot center dot center dot O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tertbutyl groups.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: MR Faizal II H
Date Deposited: 24 Nov 2015 02:06
Last Modified: 16 Apr 2019 11:42
URI: http://eprints.um.edu.my/id/eprint/14839

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