Wu, Xiang-Xiang and Zhu, Xin and Ma, Qiu-Juan and Ng, S.W. and Tiekink, E.R.T. (2011) (2-Bromoacetyl)ferrocene. Acta Crystallographica Section E: Structure Reports Online, 67 (12). M1875-U649. ISSN 1600-5368,

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In the title molecule, [Fe(C5H5)(C7H6BrO)], the C atoms of the substituted ring have disparate Fe-C bond lengths compared with the unsubstituted ring. In the bromoacetyl residue, the Br and O atoms are co-planar [the O-C-C-Br torsion angle is 5.7 (4)degrees] and are syn to each other. Helical supramolecular chains along the b axis are formed in the crystal structure mediated by C-H center dot center dot center dot O contacts; the carbonyl-O atom is bifurcated. The chains are linked into layers by C-H center dot center dot center dot pi (unsubstituted ring) interactions that stack along the a-axis direction.

Item Type: Article
Subjects: Q Science > QC Physics
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 07 Nov 2015 02:27
Last Modified: 30 Jan 2019 08:28
URI: http://eprints.um.edu.my/id/eprint/14628

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