Di-n-butyl{4-hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylene]benzohydrazidato-kappa O-2,N `}tin(IV)

Abu Affan, M. and Sam, N. and Ahmad, F. and Ng, S.W. (2010) Di-n-butyl{4-hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylene]benzohydrazidato-kappa O-2,N `}tin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (5). M572-U962. ISSN 1600-5368,

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The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)(2)(C18H12N2O3)],O,N,O'-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O-Sn-O = 155.2 (2)degrees]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Dr Mohd Faizal Hamzah
Date Deposited: 23 Oct 2015 02:23
Last Modified: 31 Jan 2019 01:39
URI: http://eprints.um.edu.my/id/eprint/14271

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