[(Z)-Ethyl N-isopropylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-Ethyl N-isopropylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (6). M615-U220. ISSN 1600-5368,

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The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S, P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44 (5)degrees],with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.023 (4) angstrom]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.

Item Type: Article
Subjects: Q Science > QD Chemistry
Depositing User: Mr Faizal 2
Date Deposited: 16 Apr 2015 08:27
Last Modified: 30 Jan 2019 09:00
URI: http://eprints.um.edu.my/id/eprint/13269

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