[mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate

Ho, S.Y. and Tiekink, E.R.T. (2010) [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (6). M608-U181. ISSN 1600-5368,

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The binuclear title compound, [Au(2)Fe(C(9)H(10)NOS)(2)(C(17)H(14)P)(2)]center dot CH(2)Cl(2),which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1: 1 dichloromethane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1-Au-P1 angle is 175.35 (5)degrees] which is due to an intramolecular Au center dot center dot center dot O contact [3.080 (5) angstrom]. The primary intermolecular contacts between binuclear molecules are of the type C-H center dot center dot center dot pi, and are arranged so as to form columns in the a-axis direction in which the disordered solvent molecules reside.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 07 Apr 2015 08:48
Last Modified: 31 Jan 2019 04:23
URI: http://eprints.um.edu.my/id/eprint/13218

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