Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]

Vafaee, M. and Amini, M.M. and Ng, S.W. (2010) Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M964-U947. ISSN 1600-5368,

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The SnIV atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octahedral coordination [C-Sn-C = 157.83 (8)degrees]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak intermolecular C-H...Cl hydrogen bonding links the molecules, forming supramolecular chains running along [100].

Item Type: Article
Subjects: Q Science > QD Chemistry
Depositing User: Mr Faizal 2
Date Deposited: 04 Feb 2015 02:12
Last Modified: 30 Jan 2019 08:32

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