(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)

Awang, N. and Baba, I. and Yamin, B.M. and Ng, S.W. and Tiekink, E.R.T. (2010) (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1144-U948. ISSN 1600-5368,

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The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H center dot center dot center dot S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H center dot center dot center dot pi interactions.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 27 Jan 2015 07:54
Last Modified: 31 Jan 2019 01:13
URI: http://eprints.um.edu.my/id/eprint/12409

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