Gunasekaran, N. and Karvembu, R. and Ng, S.W. and Tiekink, E.R.T. (2010) 1-Benzoyl-3,3-dibutylthiourea. Acta Crystallographica Section E: Structure Reports Online, 66 (10). O2601-U829. ISSN 1600-5368,

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The title molecule, C(16)H(24)N(2)OS, is twisted about the central N(H)-C bond with a C-N(H)-C-N torsion angle of -62.67 (15)degrees. The carbonyl group is twisted out of the plane of the benzene ring, forming a C-C-C=O torsion angle of -25.06 (17)degrees. In the crystal, molecules related by centres of symmetry are linked by pairs of intermolecular N-H center dot center dot center dot S hydrogen bonds, forming eight-membered {center dot center dot center dot HNCS}(2) synthons. These are further connected by weak via C-H center dot center dot center dot O contacts, forming a two-dimensional array in the bc plane.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:42
Last Modified: 31 Jan 2019 04:12
URI: http://eprints.um.edu.my/id/eprint/12215

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