catena-Poly[[triphenyltin(IV)]-mu(2)-[3-(cyclohexylcarbamoy)propan oato-kappa O-2(1):O-3]]

Shams-ul-Islam, S. and Bhatti, M.H. and Imtiaz-ud-Din, A. and Ng, S.W. and Tiekink, E.R.T. (2010) catena-Poly[[triphenyltin(IV)]-mu(2)-[3-(cyclohexylcarbamoy)propan oato-kappa O-2(1):O-3]]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1266-U920. ISSN 1600-5368,

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The Sn atom in the polymeric title compound, [Sn(C6H5)(3)-(C10H16NO3)](n), is five-coordinated within a trans-C3O2 donor set that defines an approximate trigonal-bipyramidal geometry. The carboxylate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intramolecular carboxylate-carbonyl N-H center dot center dot center dot O hydrogen bond is responsible for the curved conformation within the carboxylate ligand.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:41
Last Modified: 30 Jan 2019 09:12

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