2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate

Ou, Guang-Chuan and Ng, S.W. (2010) 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1295-U1167. ISSN 1600-5368,

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In the title salt, [Ni(C7H6NO2)(C16H36N4)]ClO4 center dot H2O, the Ni-II cation is O,O'-chelated by the benzoate anion andN,N',N `',N'''-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:41
Last Modified: 31 Jan 2019 05:10
URI: http://eprints.um.edu.my/id/eprint/12202

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