[2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)

Li, Xiao-Ping and Zhao, Jian-She and Ng, S.W. (2010) [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1297-U1175. ISSN 1600-5368,

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The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the N-pyridyl-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu-II atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway).

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:45
Last Modified: 31 Jan 2019 04:39
URI: http://eprints.um.edu.my/id/eprint/12196

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