[2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II)

Li, Xiao-Ping and Zhao, Jian-She and Ng, S.W. (2010) [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1299-U1195. ISSN 1600-5368,

Full text not available from this repository.


In the molecule of the title compound, [FeCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe-II atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.938 (11):0.062 (11) ratio. Intermolecular C-H center dot center dot center dot Cl hydrogen bonding occurs in the crystal structure.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 19 Jan 2015 03:47
Last Modified: 31 Jan 2019 04:38
URI: http://eprints.um.edu.my/id/eprint/12194

Actions (login required)

View Item View Item