3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one

Reddy, B.P. and Vijayakumar, V. and Sarveswari, S. and Ng, S.W. and Tiekink, E.R.T. (2010) 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one. Acta Crystallographica Section E: Structure Reports Online, 66 (11). O2806-U120. ISSN 1600-5368,

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Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)(2) atoms. The hydroxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intramolecular O-H center dot center dot center dot O hydrogen bonds. In the crystal, the presence of C-H center dot center dot center dot O contacts leads to the formation of supramolecular chains along the b axis. These aggregate into layers that stack along c.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 15 Jan 2015 03:38
Last Modified: 31 Jan 2019 05:17
URI: http://eprints.um.edu.my/id/eprint/12035

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