Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate

Keng, T.C. and Lo, K.M. and Ng, S.W. (2010) Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1372-U352. ISSN 1600-5368,

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The crystal structure of the title salt, [Sn(C7H7)(3)(C18H15AsO)(2)][B(C6H5)(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C3SnO2 trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0 (3)degrees and O-Sn-O angle 173.1 (1)degrees]. The structure contains voids of 113 (19) angstrom(3), but no solvent molecule could reasonably be located there.

Item Type: Article
Subjects: Q Science > Q Science (General)
Depositing User: Mr Faizal 2
Date Deposited: 14 Jan 2015 02:16
Last Modified: 31 Jan 2019 04:31

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