Ariffin, Azhar and Khan, M.N. and Cheong, M.Y. (2007) Kinetic coupled with UV spectral evidenc for near-irreversible nonionic micellar binding of n-benzylphthalimide under the typical reaction conditions: an observation against a major assumption of the pseudophase micellar model. Journal of Physical Chemistry B, 111 (42). pp. 12185-12194. ISSN 1520-6106, DOI https://doi.org/10.1021/jp073980j.
Full text not available from this repository.Abstract
Pseudo-first-order rate constants (k(obs)) for alkaline hydrolysis of N-benzylphthalimide (1) show a nonlinear decrease with the increase in [C,,,E,,]T (total concentration of Brij 58, m = 16, n = 20 and Brij 56, nt = 16, n = 10) at constant [CH3CN] and [NaOH]. These nonionic micellar effects, within the certain typical reaction conditions, have been explained in terms of the pseudophase micellar (PM) model. The values of micellar binding constants (K-s) of I are 1.04 x 101 M-(1) (at 1.0 x 10-(3) M NaOH) and 1.08 x 10(3) M-(1) (at 2.0 x 10-(3) M NaOH) for C16E20 as well as 600 M-1 (at 7.6 x 10-(4) M NaOH) and 670 M-1 (at 1.0 x 10-3 M NaOH) for C16E10 micelles. The pseudo-first-order rate constants (km) for hydrolysis of I in C16E20 micellar pseudophase are similar to 90-fold smaller than those (k(w)) in water phase. The values of km for hydrolysis of 1 in C16E10 micelles are almost zero. Kinetic coupled with UV spectral data reveals significant irreversible nonionic micellar binding of I molecules in the micellar environment of nearly zero hydroxide ion concentration at :>= 0.14 M C16E20 and 1.0 x 10-3 M NaOH while such observations could not be detected at :<= O.17 M C16E20 and 2.0 x 10-(3) M NaOH., Significantly, such irreversible C16E10 micellar binding of I molecules could be detected at 8.8 x 10-(2) M C16E10 and 1.0 x 10-3 M NaOH as well as at >= 3 x 10-3 M C16E10 and 7.6 x 10-(4) M NaOH, while the rate of hydrolysis of 1 is completely ceased at >= 0.05 M C16E10 and 7.6 x 10-(4) M NaOH. The rate of hydrolysis of 1 at 5.0 x 10-2 and 8.8 x 10-2 M C16E10 and 1.0 x 10-3 M NaOH reveals the formation of presumably phthalic anhydride, whereas such observation was not observed in the C16E20 micellar system under similar experimental conditions.
| Item Type: | Article |
|---|---|
| Funders: | UNSPECIFIED |
| Additional Information: | Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA |
| Uncontrolled Keywords: | Benzene Derivatives/*chemistry, Hydrolysis, Kinetics, *Micelles, *Models, Chemical, Phthalimides/*chemistry, Spectrophotometry, Ultraviolet |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry |
| Depositing User: | Miss Malisa Diana |
| Date Deposited: | 03 Jul 2013 09:00 |
| Last Modified: | 27 Aug 2019 06:12 |
| URI: | http://eprints.um.edu.my/id/eprint/8050 |
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