Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) bis(4-methylbenzoate) monohydrate

Tan, Kong Wai and Ng, S.W. and Tajidi, N.S.A. and Abdullah, N. and Arifin, Z. (2010) Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) bis(4-methylbenzoate) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66. M890-U314. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810026012.

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Abstract

The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(8)H(7)O(2))(2)center dot H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type of tetragonally distorted octahedral geometry. The cations, anions and lattice water molecules are linked by N-H...O and O-H...O hydrogen bonds to form a layer structure parallel to (001).

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	1,4,8,11-tetraazacyclotetradecane (cyclam) ligand; Jahn-Teller-type; Tetragonally distorted octahedral geometry; Lattice water molecules; Hydrogen bonds
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	03 Jul 2013 09:37
Last Modified:	30 Jan 2019 08:37
URI:	http://eprints.um.edu.my/id/eprint/8032

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