Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate

Tan, Kong Wai and Ng, S.W. and Maah, Mohd Jamil and Ng, C.H. (2009) Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate. Acta Crystallographica Section E: Structure Reports Online, 65. M549-U774. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809013385.

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Abstract

The two Zn-II atoms in the title compound, [Zn-2(C10H12N3O2S)(2)Cl-2]center dot 3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn2O2 core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydroxy-DMSO (DMSO is dimethyl sulfoxide) O-H center dot center dot center dot O and amide-DMSO N-H center dot center dot center dot O hydrogen bonds link the components of the crystal structure. Two of the DMSO molecules are partially disordered, with each modelled over two sites of equal weight.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	10 Jul 2013 00:35
Last Modified:	30 Jan 2019 08:53
URI:	http://eprints.um.edu.my/id/eprint/6959

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