1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)

Tan, Kong Wai and Ng, S.W. and Maah, Mohd Jamil and Ng, C.H. (2009) 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1). Acta Crystallographica Section E: Structure Reports Online, 65. M920-U922. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809026245.

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Abstract

The Zn-II atom in the title compound, [Zn(C14H11N3O2S)-(C12H8N2)]center dot 0.5C(10)H(8)N(2), is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4 '-bipyridine, which is located about a center of inversion, resulting in the formation of a supramolecular trimeric unit.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	09 Jul 2013 08:06
Last Modified:	30 Jan 2019 09:06
URI:	http://eprints.um.edu.my/id/eprint/6958

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