Bis{μ-2-(1H-indol-3-yl)-N'-[1-(5-methyl-2-oxidophen-yl)ethyl-idene]-aceto-hydraz-idato}bis-[aqua-zinc(II)] dimethyl sulfoxide tetra-solvate

Zuraini, Kadir and Ali, Hapipah Mohd and Puvaneswary, Subramaniam and Robinson, Ward T. and Ng, Seik Weng (2008) Bis{μ-2-(1H-indol-3-yl)-N'-[1-(5-methyl-2-oxidophen-yl)ethyl-idene]-aceto-hydraz-idato}bis-[aqua-zinc(II)] dimethyl sulfoxide tetra-solvate. Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 8). m1047. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536808022034.

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Abstract

The dinuclear title compound, [Zn(2)(C(19)H(17)N(3)O(2))(2)(H(2)O)(2)]·4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydr-oxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal. The coordination geometry is square-pyramidal, with the apical site occupied by a water mol-ecule. Hydrogen bonds, with the water mol-ecule serving as donor atom, lead to the formation of a linear chain motif. There is an N-H⋯O hydrogen bond between the complex molecule and solvent O atom.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	08 Apr 2013 01:59
Last Modified:	14 Dec 2020 04:25
URI:	http://eprints.um.edu.my/id/eprint/5463

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