Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate

Khaledi, H. and Ng, S.W. and Ali, Hapipah Mohd (2008) Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate. Acta Crystallographica Section E: Structure Reports Online, 64. M1615-U1249. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536808038580.

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Abstract

In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]center dot 2C(3)H(7)NO, the Ni atom (site symmetry (1) over bar) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)degrees. In the crystal structure, an N-H center dot center dot center dot O hydrogen bond links the complex to the dimethylformamide solvent molecule.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Uncontrolled Keywords:	Schiff-Base Ligand; Crystal-Structure; Nickel(Ii) Complex; Metal-Complexes
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	09 Apr 2013 08:35
Last Modified:	29 Jan 2019 08:17
URI:	http://eprints.um.edu.my/id/eprint/5460

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