{N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II). Acta Crystallographica Section E: Structure Reports Online, 67. M930-U1031. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022057.

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Abstract

The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Schiff base and one N-bound thiocyanate ligand. The second N-donor thiocyanate group, located at the apical site, completes the coordination environment. In the crystal, intermolecular C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. Intramolecular C-H center dot center dot center dot N interactions are also observed.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	25 Mar 2013 02:00
Last Modified:	30 Jan 2019 00:47
URI:	http://eprints.um.edu.my/id/eprint/5250

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