Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate

Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 67. M334-U503. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811004892.

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Abstract

In the title compound, [CuCl2(C13H19N3O)]center dot H2O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu-II ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H center dot center dot center dot Cl hydrogen bonds link the complex molecules and the uncoordinated water molecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions.

Item Type: Article
Funders: UNSPECIFIED
Additional Information: Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Department of Chemistry
Depositing User: Miss Malisa Diana
Date Deposited: 25 Mar 2013 01:56
Last Modified: 31 Jan 2019 04:12
URI: http://eprints.um.edu.my/id/eprint/5245

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