2-{ 2-(Piperazin-4-ium-1-yl)ethyliminio methyl}phenolate 0.06-chloride 0.94-perchlorate

Reisi, M.R. and Ali, Hapipah Mohd and Khaledi, H. (2011) 2-{ 2-(Piperazin-4-ium-1-yl)ethyliminio methyl}phenolate 0.06-chloride 0.94-perchlorate. Acta Crystallographica Section E: Structure Reports Online, 67. O2986-U940. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811042255.

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Abstract

The structure of the title salt, C13H20N3O+center dot 0.94ClO(4)(-)center dot 0.06Cl(-), contains a zwitterionic Schiff base with a net positive charge and a perchlorate anion having substitutional disorder with Cl. In the cation, the azomethine N atom is protonated and donates hydrogen bonds to the phenolate O atom and to the tertiary N atom of the piperazine ring. In the crystal, two Schiff base molecules are linked about a center of inversion by a pair of N-H center dot center dot center dot O hydrogen bonds. The resulting dimers are N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonded to the perchlorate anions, forming a three-dimensional structure. The network is further consolidated by C-H center dot center dot center dot pi interactions.

Item Type:	Article
Funders:	UNSPECIFIED
Additional Information:	Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Department of Chemistry
Depositing User:	Miss Malisa Diana
Date Deposited:	21 Mar 2013 01:58
Last Modified:	30 Jan 2019 01:11
URI:	http://eprints.um.edu.my/id/eprint/5206

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