Upgrading bio-oil production via catalytic co-pyrolysis of oil palm empty fruit bunch and low-density polyethylene using clinoptilolite catalyst

Al-Maari, Mohammed Abobakr and Ahmad, Mohd Azmier and Din, Azam Taufik Mohd and Hassan, Hamizura and Alsobaai, Ahmed Mubarak (2025) Upgrading bio-oil production via catalytic co-pyrolysis of oil palm empty fruit bunch and low-density polyethylene using clinoptilolite catalyst. Journal of Analytical and Applied Pyrolysis, 186. p. 106937. ISSN 0165-2370, DOI https://doi.org/10.1016/j.jaap.2024.106937.

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Abstract

The cost-effective upgradation of pyrolysis oil is a significant challenge that hinders the commercial production of biomass biofuels. This research aimed to enhance bio-oil production by co-feeding low-density polyethylene (LDPE) with palm oil empty fruit bunch (EFB) waste using a natural clinoptilolite catalyst in a fixed-bed reactor. The impact of pyrolysis temperature and the catalyst-to-feedstock (C/F) ratio on the yields and chemical composition of the bio-oil were examined. Clinoptilolite significantly enhanced the yield of the bio-oil as well as its chemical composition. The maximum yield of bio-oil (72.6 %) with a yield of hydrocarbons (77.6 %) were attained at 500 degrees C, using a C/F mass ratio of 0.2. Liquid oil produced using clinoptilolite catalyst exhibited a high heating value (HHV) (44.2MJ/kg), which is comparable to conventional diesel.

Item Type: Article
Funders: Lotte Chemical Titan (M) Sdn Bhd, Pasir Gudang, Johor, Malaysia, Universiti Sains Malaysia (304/PJKIMIA/6050422/L128)
Uncontrolled Keywords: Co-pyrolysis; Catalytic; Zeolite; Clinoptilolite; Renewable; Clean fuel; EFB; LDPE
Subjects: T Technology > TP Chemical technology
Divisions: Faculty of Engineering > Department of Chemical Engineering
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 16 Apr 2025 07:34
Last Modified: 16 Apr 2025 07:34
URI: http://eprints.um.edu.my/id/eprint/48055

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