Converting Candlenut Shell Waste into Graphene for Electrode Applications

Siburian, Rikson and Tarigan, Kerista and Manik, Yosia Gopas Oetama and Hutagalung, Fajar and Alias, Yatimah and Chan, Yong Ching and Chang, Boon Peng and Siow, Jonathan and Ong, Amanda Jiamin and Huang, Jingfeng and Paiman, Suriati and Goh, Boon Tong and Simatupang, Lisnawaty and Goei, Ronn and Tok, Alfred Iing Yoong and Yahya, Mohd Fakharul Zaman Raja and Bahfie, Fathan (2024) Converting Candlenut Shell Waste into Graphene for Electrode Applications. Processes, 12 (8). p. 1544. ISSN 2227-9717, DOI https://doi.org/10.3390/pr12081544.

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Official URL: https://doi.org/10.3390/pr12081544

Abstract

Graphene was synthesized through a two-step pyrolysis method using waste candlenut (Aleurites moluccanus) shells as the precursor. Cerium (Ce)/graphene composites were prepared via an impregnation technique. The resulting graphene and Ce/graphene were characterized using various analytical methods, including Scanning Electron Microscopy with Energy-Dispersive Spectroscopy (SEM-EDS), X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), Thermo Gravimetric Analysis (TGA), Fourier Transform Infrared (FTIR) spectroscopy, Cyclic Voltammetry (CV), and Linear Sweep Voltammetry (LSV). The bio-carbon produced predominantly exhibited a graphene structure with flat carbon morphology and an interlayer distance of 0.33 nm. This structural information is supported by XRD data, which shows a broad and weak peak at 2 theta = 26 degrees corresponding to the C (002) plane, indicative of graphene presence. FTIR, XPS, and Raman spectroscopy further confirmed the presence of graphene through the detection of Csp2 aromatic bonds and the characteristic D, G, and 2D peaks. Notably, the performance of cerium can be enhanced by the incorporation of graphene, attributed to the large surface area and chemical interactions between Ce and graphene. Consequently, candlenut-derived graphene shows potential as a supportive material for modifying the properties of cerium, due to the current value of Ce/Graphene increase with presence of graphene, thereby opening avenues for various advanced applications, such as sustainable and high-performance energy storage systems.

Item Type: Article
Funders: University of Sumatera Utara and DAPT-LPDP, University of Sumatera Utara, DAPT-LPDP under the scheme Penelitian Aliansi Internasional-WCU (3721/UN5.1) ; (R/SK/PPM/2022), SK Rektor USU
Uncontrolled Keywords: graphene; candlenut (Aleurites moluccanus) shell; Ce/graphene; carbon large scale production; energy storage electrodes
Subjects: Q Science > Q Science (General)
Q Science > QC Physics
Divisions: Faculty of Science
Faculty of Science > Department of Physics
Depositing User: Ms. Juhaida Abd Rahim
Date Deposited: 07 Apr 2025 07:36
Last Modified: 07 Apr 2025 07:36
URI: http://eprints.um.edu.my/id/eprint/46744

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