Zulkepli, Suraya and Rahman, Noorsaadah Abd. and Lee, Hwei Voon and Cheng, Chin Kui and Chen, Wei-Hsin and Juan, Joon Ching (2022) Synergistic effect of bimetallic Fe-Ni supported on hexagonal mesoporous silica for production of hydrocarbon-like biofuels via deoxygenation under hydrogen-free condition. ENERGY CONVERSION AND MANAGEMENT, 273. ISSN 1879-2227, DOI https://doi.org/10.1016/j.enconman.2022.116371.
Full text not available from this repository.Abstract
The need to explore a sustainable manner to produce hydrocarbon-like biofuel has attracted tremendous interest. A series of bimetallic catalysts comprised of Fe and Ni with different Ni loadings supported on hexagonal mesoporous silica (HMS) were synthesized for the production of hydrocarbon-like biofuel via deoxygenation (DO) reaction without the use of external hydrogen. The bimetallic 10Fe40Ni/HMS catalyst possesses a high conversion (96.1%) and selectivity towards C8-C20 hydrocarbon (91.8%) during the DO reaction. This is because the finely dispersed Fe and Ni consisting of NiO and NiFe2O4 demonstrate strong acidity along with higher amount of Bro center dot nsted-Lewis acid properties. The DO reaction of triglycerides with bimetallic Fe and Ni supported on HMS is a sustainable process to produce hydrocarbon biofuel.
| Item Type: | Article |
|---|---|
| Funders: | Ministry of Education, Malaysia [FRGS/1/2017/STG01/UM/02/12], Universiti Malaya |
| Uncontrolled Keywords: | Bimetallic; Mesoporous; Deoxygenation; Hydrocarbon; Biofuels |
| Subjects: | T Technology > TP Chemical technology |
| Divisions: | Nanotechnology & Catalysis Research Centre Institute of Advanced Studies |
| Depositing User: | Ms Koh Ai Peng |
| Date Deposited: | 25 Oct 2024 02:25 |
| Last Modified: | 25 Oct 2024 02:25 |
| URI: | http://eprints.um.edu.my/id/eprint/46185 |
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