Sazeli, Syabilah and Hamisu, Aliyu Mohammed and Sagadevan, Suresh and Chee, Chin Fei and Johan, Mohd Rafie (2024) Unveiling a new chain-based two-dimensional zinc-organic framework with thiadiazolyl dicarboxylic acid ligands and their characterization. Journal of Molecular Structure, 1306. p. 137910. ISSN 0022-2860, DOI https://doi.org/10.1016/j.molstruc.2024.137910.
Full text not available from this repository.Abstract
A new two-dimensional (2D) zinc (Zn)-based coordination polymer, denoted as UMMOF-1, with a framework composition {Zn(TBA)(mu-H2O)(H2O)2}n (where TBA = 4,4 `-(((1,3,4-thiadiazole-2,5-diyl)bis(sulfanediyl))bis (methylene))dibenzoate), was successfully synthesized at room temperature using the slow diffusion method. UMMOF-1 is the first Zn-MOF to exhibit a monodentate binding mode with the TBA ligand. Single-crystal X-ray diffraction (SC-XRD) analysis revealed that UMMOF-1 crystallized in a monoclinic crystal structure with the space group C12/c1. The structure consisting 1D inorganic chains interconnected into a 2D zigzag framework, was alternately packed along the b-axis. Interestingly, UMMOF-1 features has various uncoordinated functional groups, including O, S, and N, that are suitable for adsorption and catalytic applications. SC-XRD, PXRD, FESEM, TGA, and FT-IR are used to confirm the crystallinity, morphology, thermal stability, and the presence of various functional groups in the UMMOF-1. Furthermore, the stability of UMMOF-1 towards water exhibited remarkable adsorption capabilities for the methylene blue (MB) dye, a common water contaminant. UMMOF-1 demonstrates superior performance compared to its organic ligand (H2TBA), highlighting its potential for environmental remediation and wastewater treatment.
| Item Type: | Article |
|---|---|
| Funders: | Ministry of Education, Malaysia (FP127-2019A) |
| Uncontrolled Keywords: | Zinc-organic framework; 2D-MOF; 4-thiadiazole dicarboxylic acid; Slow diffusion; Methylene blue adsorption |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Department of Chemistry Deputy Vice Chancellor (Research & Innovation) Office > Nanotechnology & Catalysis Research Centre |
| Depositing User: | Ms. Juhaida Abd Rahim |
| Date Deposited: | 22 Oct 2024 07:09 |
| Last Modified: | 22 Oct 2024 07:09 |
| URI: | http://eprints.um.edu.my/id/eprint/45479 |
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